page 74
ESSENTIAL ELEMENTS, MOBILITY AND pH EFFECT

essential element - an element required by plants for normal growth, development and completion of
                                its life cycle, and which cannot be substituted for by other chemical compounds.

17 ELEMENTS ARE REQUIRED BY PLANTS
 3 supplied naturally by air and water - comprise the bulk of the plant 
    C, H, 0 
 6 macronutrients - required at 0.1 to 6% of the dry weight of plants 
    N, P, K, S, Ca, Mg
 8 micronutrients - required at 1 to 300 ppm of the dry weight of plants 
    Fe, Zn, Cu, Mo, B, Mn, Cl, Ni
    Cl and Ni are ubiquitous - hence, will not be addressed in detail 

The essential elements can be easily remembered by a catch phrase such as 
C. HOPKiNSCaFe, CuB, Mn, C.l. MoNiZnsky, Mgr
 

NUTRIENT MOBILITY
Two directions of movement in plants
1) acropetal - means towards the apex; transport up in the xylem 
2) basipetal - means towards the base; transport down in the phloem 

Two classifications of nutrient mobility
1) mobile - moves both up and down the plant by both acropetal and basipetal  transport (in both 
                  the xylem and phloem).
                - deficiency appears on older leaves first. 
    N, P, K, Mg, S
2) immobile - moves up the plant by only acropetal (in the xylem) transport. 
                    - deficiency appears on new leaves first. 
    Ca, Fe, Zn, Mo, B, Cu, Mn
 

EFFECT OF pH
The pH determines solubility in the soil
1) more available at low pH (below 5.5), and less available at high pH.
    Fe, Zn, Cu, Mn, B
2) more available at high pH (above 6.5), and less available at low pH.
    N, K, Mg, Ca, S, Mo 
3) more available at intermediate pH (6-7) 
    P  

pH Nutrient
                        availability
Ideal pH:
slightly acid:

a) around 6.5 for field soil 
b) around 5.5-6.0 for artificial growing media made with peat moss or composted bark


page 75
FERTILIZER ANALYSIS AND RATIO

FERTILIZER ANALYSIS

analysis - sequence of 3 numbers on the fertilizer label that gives the percent composition
                of N-P205-K20 in a fertilizer; required by law to be on the label of every fertilizer sold.


Example:
 8-8-8
means the fertilizer contains
:

8% N 
     8% P20
    8% K2
24% total nutrient content 

8-8-8
                      analysis fertilizer

          Buy fertilizers by price per pound of fertilizer, not price per bag.

100 lb. of 8-8-8 @ $4.99
100 lb. @ 24% = 24 lb. of nutrients
@ $4.99 = 20.8 cents per lb
100 lb. of 13-13-13 @ $5.99
100 lb @ 39% = 39 lb. of nutrients
@ $5.99 = 15.3 cents per lb.
   

FERTILIZER RATIO

ratio - the relative proportion of N to P205 to K20 in a fertilizer.

Analysis 
8-8-8
20-20-20
10-20-10 
18-6-12
Ratio 
1-1-1
1-1-1
1-2-1 
3-1-2
  

USING FERTILIZER RATIOS TO MANIPULATE PLANT GROWTH

a) to favor vegetative growth

  • use a high N, low P and K fertilizer 
  • for example, use a 2-1-1 or 3-1-1 ratio fertilizer (higher 1st number) 
b) to favor flowering, root and underground storage organ growth
  • use a low N, high P and/or K fertilizer 
  • for example, use a 1-2-2 or 1-3-2 ratio fertilizer (higher 2nd and/or 3rd number) 

page 76
FUNCTION OF NUTRIENTS

Nutrient  Symbol Function
nitrogen
N
1) Component of chlorophyll; amino acids, proteins and enzymes; 
    nucleic acids (RNA and DNA); some auxins and cytokinins. 
phosphorus
P
1) Component of the high energy compounds ATP, NADPH and NADP; nucleic acids (DNA and RNA); and phospholipids. 
potassium
K
1) Needed for protein and enzyme synthesis and activation. 
2) Involved in maintaining proper water balance 
3) Needed for photosynthesis.
magnesium
Mg
1) Component of chlorophyll. 
2) Activates many enzymes.
calcium
Ca
1) Ca pectates in middle lamella of cell wall cement cells together. 
2) Required for normal cell division and meristem growth. 
3) Stabilizes membranes
sulfur
S

1) Component of several amino acids (methionine, cystine, cysteine). 
iron
Fe
1) Required for chlorophyll synthesis. 
2) Component of many enzymes/carriers, especially those of electron  transport chain.
zinc
Zn

1) Required for tryptophan, hence auxin (IAA), synthesis. 
manganese
Mn
1) Required for chlorophyll synthesis. 
2) Activates many enzymes.
copper
Cu
1) Required for chlorophyll synthesis.
2) Component of many enzymes/carriers, esp. of electron transport chain. 
boron
B
1) Required for complete flowering and fruit development. 
2) Involved in translocation of carbohydrates and hormones.
molybdenum
Mo
1) Component of enzymes in N metabolism (nitrate to organic N) 
2) Component of enzymes in nitrogen fixation (N gas to ammonia) 
chlorine
Cl
1) Oxygen evolution in photosynthesis 
2) Stomatal functioning 
nickel
Ni

1) Component of several enzymes, especially urease (breaks down urea) 
 

page 77
TISSUE CONCENTRATION, DEFICIENCY SYMPTOMS AND FERTILIZER SOURCES

Nutrient
Tissue Concentration
Characteristic Deficiency Symptom*
Fertilizer Sources
MACRONUTRIENTS
N
2-6%
older leaves - overall chlorosis NH4 nitrate, sulfate, phosphate;
K, Na, or Ca nitrate; urea 
P
0.2-1.2%
older leaves - deep green, purple coloration of petioles superphosphate; NH4 or K phosphate; phosphoric acid 
K
1-6% 
(luxury 
consumption)
older leaves - interveinal chlorosis with marginal and tip necrosis K nitrate, chloride, phosphate, or sulfate; K frit 
Mg
 0.2-1%
older leaves - interveinal chlorosis and bronze coloration dolomite (Ca/Mg carbonate), 
Mg sulfate (Epsom salt)
Ca
0.5-2%
stem tips - die, small leaves limes (Ca carbonate/hydroxide);
Ca sulfate (gypsum) or nitrate; 
superphosphate
S
0.3-0.7%
all leaves overall chlorosis, on young leaves 1st then progresses to old leaves sulfate carriers; elemental S; 
air pollution; superphosphate
MICRONUTRIENTS**
Fe
50-300 ppm
young leaves - severe interveinal chlorosis  Fe chelate; Fe sulfate; some pesticides 
Zn
5-75 ppm
new growth - rosetted growth & small leaves Zn chelate; Zn sulfate; 
some pesticides
Mn
30-300 ppm
young leaves - interveinal chlorosis with necrosis when severe Mn chelate; Mn sulfate; 
some pesticides
Cu
5-30 ppm
stem tips - die, stunted; leaves small; multiple buds formed Cu chelate; Cu sulfate; 
some pesticides
B
30-200 ppm
stem tips - internodes short, thick; leaves thick, brittle, with necrosis borax; boric acid
Mo
1 ppm
similar to N deficiency, except occurs on young leaves. Na or NH4 molybdate 
Cl and 
Ni
?
virtually never seen in nature ubiquitous
*chlorosis = yellowing;  necrosis = browning;  interveinal = between the veins
**micronutrients are often applied as a micronutrient mix (ex. Micromax) or complete plus micronutrients (Miracle Gro)

page 78
NUTRIENTS WITH SIMILAR DEFICIENCY SYMPTOMS

Nutrients That Cause Interveinal Chlorosis

Deficiency Of
 Interveinal Chlorosis Occurs On
 With No Necrosis
 Plus Necrosis
Young Leaves
Fe
Mn
Old Leaves
Mg
K
 
Nutrients That Cause Overall Chlorosis
Overall Chlorosis Occurs on
Deficiency Of
Old Leaves
N
New Leaves
Mo
New Leaves, Then Spreading to Old Leaves
S
 
Nutrients That Effect the Shoot Tip
Various Deficiency Symptoms
on Growing Point, Emerging Leaves or Shoot Tip 
Deficiency Of
Small New Leaves and Rosetted New Growth
Zn
Thick and Brittle New Leaves
B
New Leaves Distorted and Necrotic
Ca
Vague Symptoms: New Leaves Small, Wilted, Translucent or Necrotic
Cu
 

page 79
NITROGEN CYCLE
 
nitrogen
                cycle

WAYS IN WHICH NITROGEN IS LOST FROM THE SOIL
1) leaching (especially nitrate which is negatively charged) 
2) plant absorption
3) microorganisms consume (see C:N ratio next page) 
4) denitrification


page 80
NITROGEN CONVERSIONS

NITROGEN REACTIONS
mineralization or ammonification -the conversion of organic nitrogen (in the -NH2 form) to
                                                       inorganic nitrogen (in the NH4 form).
                                                     - the speed of conversion depends on the C:N ratio (see below).

nitrification - a two step process converting ammonium to nitrite, then nitrite to nitrate.
                   - the soil bacterium Nitrosomonas converts ammonium to nitrite
                   - the soil bacterium Nitrobacter converts nitrite to nitrate
                   - this occurs very quickly so little ammonium (which can be toxic if high) and
                     virtually no nitrite (which is highly toxic) accumulates in the soil.

denitrification - the conversion of nitrate in the soil to gaseous nitrogen that escapes into the
                         atmosphere.

nitrogen fixation - the conversion of gaseous nitrogen to ammonia.
                           - only nitrogen fixing microorganisms can cause nitrogen fixation; 
                             some form symbiotic relationships with plants (see table below)
 

CARBON:NITROGEN (C:N) RATIOS IN ORGANIC MATTER
 C:N ratio - proportion  of carbon to nitrogen present in organic matter. 

a) high C:N ratio - wood, sawdust, uncomposted bark 
    - microbes use up all nitrogen in organic matter when consuming carbon, 
    - then the microbes use up the nitrogen in the soil 

b) low C:N ratio - manure, bone meal, fish emulsion, organic fertilizers 
    - microbes consume carbon, 
    - then release excess nitrogen from the organic matter into the soil 
    - thus, low C:N organic matter acts as an organic nitrogen fertilizer

C:N of Organic Matter

30:1 approx cut-off for net N release or depletion

Organic Matter
C:N
Effect on N

chicken manure

7:1

Low C:N Ratio
Net nitrogen release into the soil
Acts as an
organic N fertilizer

bat guano

10:1

alfalfa fresh cut

12:1

mushroom compost

13:1

cow manure

15:1

grass clippings

20:1

  horse manure
25:1

rye grass cover crop

26:1

leaves

60:1

High C:N Ratio
Net nitrogen depletion
Acts as a N un-fertilizer

pine needles

80:1

bark uncomposted

223:1

saw dust or wood chips

200-500:1

 

MICROORGANISMS THAT CAN FIX NITROGEN
 
Type Microorganism
Nitrogen-Fixing 
Microorganism
Forms Symbiotic
Relationship With
1) Bacteria 
Rhizobium
Legumes
(soybean, clover, mesquite)
2) Bacteria 
Azotobacter 
Clostridium
free living only
3) Filamentous Bacteria
some Actinomycetes
Some woody plants 
(Alnus and Elaeagnus)
4) Blue-green algae 
Anabaena
Azolla and Cycads
(can also be free living)